Residues of thiram in grapes

Table 30. Residues of thiram (expressed as thiram) in grapes from foliar application of thiram in supervised trials in France and Germany.

Country, year (variety)

Application

PHI, days

Residues, as thiram, mg/kg

Ref.

Form

kg ai/ha

kg ai/hl

No.

CS₂ method

HPLC method

France, 1991 (Pinot Noir)

WG

3.2

0.8

1 dt

70

0.26

<0.05

FR7/91,

2 dt

44

0.33

0.11

CRP/94/1295

France, 1992 (Merlot)

WG

3.2

1.6

3

32

9.3

2.6

28203 B001

4

21

11.7

5.6

France, 1992 (Pinot)

WG

3.2

1.2

3

33

2.4

1.1

28203 B004

4

21

2.5

2.2

France, 1992 (Pinot Noir)

WG

3.2

0.6-1.1

3

48

3.0

2.7

28203 B003

4

21

7.4

4.5

France, 1992 (Cot)

WG

3.2

1.4

3

32

0.8

0.7

28203 B002

4

21

4.3

2.3

France, 1994 (Cinsault)

WG

3.2

1.1

3

0

1.9 4.3 0.9

9402/01-FPWE loc 1

10

1.5 0.8 1.2

21

0.4 0.6 0.8

28

0.1 0.6 0.4

35

0.2 0.2 0.1

France, 1994 (Merlot)

WG

3.2

1.1

3

0

4.1 5.4 7.2

9402/01-FPWE loc 2

10

6.4 5.6 5.6

21

1.8 4.0 2.4

28

1.3 1.3 1.2

35

0.2 0.5 <0.2

Germany, 1992 (Riesling)

WG

2.4

0.24

3

0

1.7 c 5.1

c 1.9

DE/FR/03/92,

21

3.0

1.1

DU3/30/92

28

3.3

0.8

35

3.0 c 1.7

0.7

Germany, 1992 (Portugieser)

WG

2.4

0.24

3

0

2.2 c 0.17

2.0

DE/FR/03/92,

21

1.6

1.0

DU3/29/92

28

1.5

0.9

35

1,0 c 0.38

0.6

Germany, 1992 (Schwarzriesling)

WG

2.4

0.24

3

0

7.0 c 1.9

3.4

DE/FR/03/92,

21

2.5

1.0

DU/60/92

28

3.0

0.6

35

3.5 c 0.76

0.9

Germany, 1992 (Muller Thurgau)

WG

2.4

0.24

3

0

3.8 c 0.76

2.5

DE/FR/03/92,

20

1.9

1.2

DU/61/92

28

2.9

0.5

34

2.7 c 0.51

1.2

c: control sample.
dt: other dithiocarbamates also applied during the growing season.

Table 31. Residues of thiram (expressed as thiram) in strawberries from foliar application of thiram in supervised trials in Belgium, France, Germany and Poland. Underlined residues are from treatments according to GAP and are valid for estimation of maximum residue levels.

Country, year (variety)

Application

PHI, days

Residues, as thiram, mg/kg

Ref.

Form

kg ai/ha

kg ai/hl

No.

CS₂ method

HPLC method

Belgium, 1991 (Elsanta, June bearing)

WP

1.6

0.23

8

0

3.0

3.3

CRP/92/863A

7

2.4

2.8

14

0.44

0.45

21

0.05

0.06

Belgium, 1991 (Selva Everbearing)

WP

1.6

0.23

3

11

0.32

0.32

CRP/92/865

4

7

0.85

0.72

5

6

1.0

0.97

6

7

1.0

0.93

7

8

1.2

1.3

8

7

1.4

1.3

9

8

1.1

1.1

10

6

1.0

0.99

11

8

1.8

0.92

12

7

1.2

1.5

Belgium, 1991 (Vicoda, June bearing)

WG

1.6

0.23

7

0

2.8

2.7

CRP/92/862A

7

1.2

1.4

14

0.82

0.87

21

0.72

0.79

Belgium, 1991 (Selva, Everbearing)

WG

1.6

0.23

3

11

0.85

1.0

CRP/92/864A

4

7

0.97

1.1

5

6

0.85

1.0

6

7

1.9

2.1

7

8

0.91

0.84

8

7

1.4

1.2

9

8

0.89

0.92

10

6

1.6

2.0

12

1

1.2

1.1

12

7

1.3

1.6

Belgium, 1992 (Selva, Everbearing)

WG

1.6 dt

0.23

5

7

2.3

BCSEL BA 7792a

6

7

2.4

7

7

0.64

8

6

2.2

9

7

1.4

10

7

1.3

11

7

1.2

12

6

1.5

13

7

4.5

14

7

5.8

Belgium, 1992 (Irvine, Everbearing)

WG

1.6

0.23

5

7

3.1

BCIRV BA 7792d

6

7

2.5

7

7

1.0

8

7

1.5

9

8

1.1

10

7

3.8

11

6

2.3

12

6

4.3

13

7

6.3

14

7

11

Belgium, 1993 (Elsanta)

WG

1.6

0,29-

6

0

16

UCB B 93-3 B27-93 9301-RU-010-1

0.41

3

1.7

7

2.1

10

1.7

14

0.45

France, 1988 (Elvira)

WG

2.2

0.22

2

14

0.70

FR5 552/6

France, 1988 (Gorella)

WG

2.2

0.29

3 dt

13

0.92

FR8 850/6

France, 1988 (Gorella)

WG

3.2

0.42

3 dt

13

1.4

FR8 850/7

France, 1988 (Elvira)

WG

3.2

0.32

2

14

0.85

FR5 552/7

France, 1988 (Gorella)

WG

3.2

0.32

2

27

1.1

FR5 551/7

France, 1988 (Gorella)

WG

2.2

0.22

2

27

0.68

FR5 551/6

France, 1989 (Gorella)

WG

2.2

0.22

2

32

<0.2

F 869/89/547

France, 1989 (Gorella)

WG

2.2

0.22

2

21

0.8

F 869/89/548

France, 1989 (Selva)

WG

2.2

0.22

2 dt

19

1.1

F 869/89/847

France, 1992 (Selva)

WG

3.2

0.32

2

0

1.3 3.7

SPV 33 02

PCT¹

2

2.8

4

2.1

8

1.6

10

1.5

14

1.4

France, 1992 (Seascape)

WG

3.2 PCT

0.32

2

0

1.2 4.1

SPV 33 01

2

2.3

4

1.7

10

0.79

14

0.71

France, 1993 (Elsanta)

WG

2.4

0.35-

4

0

7.7

UCB B93-10, 93101-RU-010-3, B93501

0.54

3

4.1

7

2.3

10

1.0

14

0.54

France, 1994 (Chandler)

WG

2.4

0.24

3

0

7.4

94020/01-FPEB loc 2

3

2.4

7

2.8

10

2.9

14

1.5

France, 1994 (Chandler)

WG

2.4

0.24

3

0

2.8 3.6 5.7

94020/01-FPEB loc 1

3

2.8 3.4 3.8

7

0.9 1.5 1.4

11

0.6 0.8 1.3

15

0.4 0.4 0.6

Germany, 1962 (Senga Sengana)

WP

0.96

0.16

1

0

0.2

BBA

3

<0.2

7

<0.2

14

<0.2

Germany, 1963 (Senga Sengana)

WP

2.4

0.4

1

3

<0.2

BBA

Germany, 1964 (Senga Sengana)

WP

0.49

0.025

3

10

0.79

BBA

Germany, 1964 (Senga Sengana)

WP

4

0.16

4

12

2.2

BBA

4

0.16

3

19

1.7

4

0.16

2

25

0.79

4

0.16

1

31

0.32

Germany, 1964 (Senga Sengana)

WP

2.4

0.4

3

10

1.7

BBA

Poland, 1994 (Senga Sengana)

WG

3.2

3

0

8.1

3

4.4

14

1.2

dt: other dithiocarbamates also applied during the growing season
¹ Outdoor, plastic covered tunnel

Country, year (variety)	Application				PHI, days	Residues, as thiram, mg/kg		Ref.
Country, year (variety)	Form	kg ai/ha	kg ai/hl	No.	PHI, days	CS₂ method	HPLC method	Ref.
France, 1991 (Pinot Noir)	WG	3.2	0.8	1 dt	70	0.26	<0.05	FR7/91,
France, 1991 (Pinot Noir)				2 dt	44	0.33	0.11	CRP/94/1295
France, 1992 (Merlot)	WG	3.2	1.6	3	32	9.3	2.6	28203 B001
France, 1992 (Merlot)				4	21	11.7	5.6	28203 B001
France, 1992 (Pinot)	WG	3.2	1.2	3	33	2.4	1.1	28203 B004
France, 1992 (Pinot)				4	21	2.5	2.2	28203 B004
France, 1992 (Pinot Noir)	WG	3.2	0.6-1.1	3	48	3.0	2.7	28203 B003
France, 1992 (Pinot Noir)				4	21	7.4	4.5	28203 B003
France, 1992 (Cot)	WG	3.2	1.4	3	32	0.8	0.7	28203 B002
France, 1992 (Cot)				4	21	4.3	2.3	28203 B002
France, 1994 (Cinsault)	WG	3.2	1.1	3	0		1.9 4.3 0.9	9402/01-FPWE loc 1
					10		1.5 0.8 1.2
					21		0.4 0.6 0.8
					28		0.1 0.6 0.4
					35		0.2 0.2 0.1
France, 1994 (Merlot)	WG	3.2	1.1	3	0		4.1 5.4 7.2	9402/01-FPWE loc 2
					10		6.4 5.6 5.6
					21		1.8 4.0 2.4
					28		1.3 1.3 1.2
					35		0.2 0.5 <0.2
Germany, 1992 (Riesling)	WG	2.4	0.24	3	0	1.7 c 5.1	c 1.9	DE/FR/03/92,
					21	3.0	1.1	DU3/30/92
					28	3.3	0.8
					35	3.0 c 1.7	0.7
Germany, 1992 (Portugieser)	WG	2.4	0.24	3	0	2.2 c 0.17	2.0	DE/FR/03/92,
					21	1.6	1.0	DU3/29/92
					28	1.5	0.9
					35	1,0 c 0.38	0.6
Germany, 1992 (Schwarzriesling)	WG	2.4	0.24	3	0	7.0 c 1.9	3.4	DE/FR/03/92,
					21	2.5	1.0	DU/60/92
					28	3.0	0.6
					35	3.5 c 0.76	0.9
Germany, 1992 (Muller Thurgau)	WG	2.4	0.24	3	0	3.8 c 0.76	2.5	DE/FR/03/92,
					20	1.9	1.2	DU/61/92
					28	2.9	0.5
					34	2.7 c 0.51	1.2